Transition-Metal-Catalyzed Trifluoromethylation of Aryl Halides

被引:182
作者
Lundgren, Rylan J. [1 ]
Stradiotto, Mark [1 ]
机构
[1] Dalhousie Univ, Dept Chem, Halifax, NS B3H 4J3, Canada
关键词
copper; cross-coupling; fluorine; homogeneous catalysis; palladium; ENANTIOSELECTIVE ALPHA-TRIFLUOROMETHYLATION; MEDICINAL CHEMISTRY; PALLADIUM; FLUORINE; ORGANOCATALYSIS; STRATEGIES; ALDEHYDES; REAGENTS;
D O I
10.1002/anie.201004051
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Making inroads into ArCF3: Recent advances in the copper- and palladium-catalyzed cross-coupling of aryl halides and the trifluoromethyl anion, derived from (trifluoromethyl)silanes, are highlighted. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:9322 / 9324
页数:3
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