High-Performance Two-Dimensional Polydiacetylene with a Hybrid Inorganic-Organic Structure

被引：60

作者：

Cho, Sangho ^{[1
]}

Han, Gibok ^{[1
]}

Kim, Kwan ^{[2
]}

Sung, Myung M. ^{[1
]}

机构：

[1] Hanyang Univ, Dept Chem, Seoul 133791, South Korea

[2] Seoul Natl Univ, Dept Chem, Seoul 151742, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 12期

关键词：

molecular electronics; polymerization; semiconductors; surface chemistry; thin films; MOLECULAR LAYER DEPOSITION; FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; POLYMERIZATION; MONOLAYER; POLYMERS; NYLON-66; GROWTH;

D O I：

10.1002/anie.201006311

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thin films not thin on the ground: The title films were grown by molecular layer deposition involving repeated sequential adsorption of diethylzinc (DEZ) and hexadiyne diol (HDD) with UV polymerization. The prepared zinc oxide cross-linked polydiacetylene films exhibited good thermal and mechanical stabilities, enhanced carrier mobility (>1.3 cm2 V-1 s), and other favorable properties owing to their 2D structures. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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页码：2742 / 2746

页数：5

相关论文

共 22 条

[1] Molecular layer deposition of poly(p-phenylene terephthalamide) films using terephthaloyl chloride and p-phenylenediamine [J].

Adarnczyk, N. M. ;

Dameron, A. A. ;

George, S. M. .

LANGMUIR, 2008, 24 (05) :2081-2089

[2] Organic non-volatile memory based on pentacene field-effect transistors using a polymeric gate electret [J].

Baeg, Kang-Jun ;

Noh, Yong-Young ;

Ghim, Jieun ;

Kang, Seok-Ju ;

Lee, Hyemi ;

Kim, Dong-Yu .

ADVANCED MATERIALS, 2006, 18 (23) :3179-+

[3] Molecular layer deposition of nylon 66 films examined using in situ FTIR spectroscopy [J].

Du, Y. ;

George, S. M. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (24) :8509-8517

[4] LOW-TEMPERATURE SURFACE CLEANING OF SILICON AND ITS APPLICATION TO SILICON MBE [J].

ISHIZAKA, A ;

SHIRAKI, Y .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1986, 133 (04) :666-671

[5] Raman microspectroscopic study on polymerization and degradation processes of a diacetylene derivative at surface enhanced Raman scattering active substrates. 2. Confocal Raman microscopic observation of polydiacetylene adsorbed on active sites [J].

Itoh, K ;

Kudryashov, I ;

Yamagata, J ;

Nishizawa, T ;

Fujii, M ;

Osaka, N .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (01) :271-276

[6] Conducting polymers in electronic chemical sensors [J].

Janata, J ;

Josowicz, M .

NATURE MATERIALS, 2003, 2 (01) :19-24

[7] Organic-inorganic hybrid materials as semiconducting channels in thin-film field-effect transistors [J].

Kagan, CR ;

Mitzi, DB ;

Dimitrakopoulos, CD .

SCIENCE, 1999, 286 (5441) :945-947

[8] Layer-by-layer growth on Ge(100) via spontaneous urea coupling reactions [J].

Kim, A ;

Filler, MA ;

Kim, S ;

Bent, SF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (16) :6123-6132

[9] Rapid vapor-phase fabrication of organic-inorganic hybrid superlattices with monolayer precision [J].

Lee, Byoung H. ;

Ryu, Min Ki ;

Choi, Sung-Yool ;

Lee, Kwang-H. ;

Im, Seongil ;

Sung, Myung M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (51) :16034-16041

[10] PHOTOLUMINESCENCE, ABSORPTION, AND RAMAN-SPECTRA OF A POLYDIACETYLENE MONOLAYER [J].

MIYANO, K ;

MAEDA, T .

PHYSICAL REVIEW B, 1986, 33 (06) :4386-4388