Rigid rod molecules containing two Si(OMe)3 or SiMe(OMe)2 groups for hybrid materials synthesis

被引:15
作者
Cerveau, G [1 ]
Chappellet, S [1 ]
Corriu, RJP [1 ]
Dabiens, B [1 ]
机构
[1] Univ Montpellier 2, UMR 5637, Lab Chim Mol & Org Solide, F-34095 Montpellier 5, France
关键词
trimethoxysilanes; methyldimethoxysilanes; synthesis; Heck reaction;
D O I
10.1016/S0022-328X(01)00668-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis of new bis(trimethoxysilyl) and bis(dimethoxymethylsilyl)arene compounds containing rigid organic groups such as stilbenyl, diphenylacetylene or diphenylbut-1,3-diyne is reported. The Heck type reaction constituted a convenient route to these compounds. since this coupling reaction appeared compatible with the presence of Si(OR)(3) groups. (C) 2001 Elsevier Science B.V. All nights reserved.
引用
收藏
页码:92 / 99
页数:8
相关论文
共 41 条
[1]   FACILE SYNTHESIS OF ETHYNYLATED BENZOIC-ACID DERIVATIVES AND AROMATIC-COMPOUNDS VIA ETHYNYLTRIMETHYLSILANE [J].
AUSTIN, WB ;
BILOW, N ;
KELLEGHAN, WJ ;
LAU, KSY .
JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (11) :2280-2286
[2]   CHEMISTRY OF TRICHLOROSILANE-TERT AMINE COMBINATIONS [J].
BENKESER, RA .
ACCOUNTS OF CHEMICAL RESEARCH, 1971, 4 (03) :94-&
[3]   PROBLEM OF CONJUGATION ACROSS A PI-BONDED SILICON ATOM IN 2-SILABUTADIENE SYSTEMS [J].
BERTRAND, G ;
MANUEL, G ;
MAZEROLLES, P ;
TRINQUIER, G .
TETRAHEDRON, 1981, 37 (16) :2875-2880
[4]   Preparation and characterization of new organic-inorganic hybrid materials incorporating phosphorus centres [J].
Bezombes, JP ;
Chuit, C ;
Corriu, RJP ;
Reye, C .
JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (08) :1749-1759
[5]  
Boury B, 1999, ANGEW CHEM INT EDIT, V38, P3172, DOI 10.1002/(SICI)1521-3773(19991102)38:21<3172::AID-ANIE3172>3.0.CO
[6]  
2-3
[7]   Structure of silica-based organic-inorganic hybrid xerogel [J].
Boury, B ;
Corriu, RJP ;
Delord, P ;
Le Strat, V .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2000, 265 (1-2) :41-50
[8]   PARA-PHENYLENEDISILANES [J].
BREED, LW ;
HAGGERTY, WJ ;
BAIOCCHI, F .
JOURNAL OF ORGANIC CHEMISTRY, 1960, 25 (09) :1633-1637
[9]   POLYFUNCTIONAL CARBOSILANES AND ORGANOSILICON COMPOUNDS - SYNTHESIS VIA GRIGNARD REACTIONS [J].
BRONDANI, DJ ;
CORRIU, RJP ;
ELAYOUBI, S ;
MOREAU, JJE ;
MAN, MWC .
TETRAHEDRON LETTERS, 1993, 34 (13) :2111-2114
[10]   A NEW TRIALKOXYSILYLATION REACTION, THE CROSS-COUPLING OF (TRI-ISOPROPYLOXYSILYL)METHYL GRIGNARD-REAGENT WITH ORGANIC HALIDES [J].
BRONDANI, DJ ;
CORRIU, RJP ;
ELAYOUBI, S ;
MOREAU, JJE ;
MAN, MWC .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 451 (1-2) :C1-C3