An efficient and general iron-catalyzed arylation of benzyl alcohols and benzyl carboxylates

被引：318

作者：

Iovel, I ^{[1
]}

Mertins, K ^{[1
]}

Kischel, J ^{[1
]}

Zapf, A ^{[1
]}

Beller, M ^{[1
]}

机构：

[1] Univ Rostock eV IFOK, Leibniz Inst Organ Katalyse, D-18055 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 25期

关键词：

arylation; benzylation; Friedel-Crafts reaction; homogeneous catalysis; iron;

D O I：

10.1002/anie.200462522

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Green grow the diarylmethanes: Substituted arenes and heteroarenes can be easily benzylated in the presence of inexpensive and relatively nontoxic metal salts such as FeCl3 (see scheme). This arylation method with benzyl alcohols is a state-of-the-art green route to diarylmethanes as water is the only by-product. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3913 / 3917

页数：5

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