Synthesis of a tricyclic mescaline analogue by catalytic C-H bond activation

被引：77

作者：

Ahrendt, KA

Bergman, RG ^{[1
]}

Ellman, JA

机构：

[1] Univ Calif Berkeley, Dept Chem, Ctr New Direct Organ Synth, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem Sci, Berkeley, CA 94720 USA

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 08期

关键词：

D O I：

10.1021/ol034228d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A tetrahydrobis(benzofuran) mescaline analogue has been prepared in six steps and 38% overall yield from (4'-O-methyl)methyl gallate. The key step in this synthesis is a tandem cyclization reaction via directed C-H activation followed by olefin insertion.

引用

页码：1301 / 1303

页数：3

共 24 条

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