CNFs@CNTs:: Superior carbon for electrochemical energy storage

被引：125

作者：

Zhang, Jian ^{[2
]}

Hu, Yong-Sheng ^{[1
]}

Tessonnier, Jean-Philippe ^{[2
]}

Weinberg, Gisela ^{[2
]}

Maier, Joachim ^{[1
]}

Schloegl, Robert ^{[2
]}

Su, Dang Sheng ^{[2
]}

机构：

[1] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany

[2] Max Planck Gesell, Fritz Haber Inst, Dept Inorgan Chem, D-14195 Berlin, Germany

来源：

ADVANCED MATERIALS | 2008年 / 20卷 / 08期

关键词：

D O I：

10.1002/adma.200701685

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon-nanotube-encapsulated carbon nanofibers (CNFs@CNTs) with a novel one-dimensional structure are synthesized via the selective assembly of CNFs inside the channels of CNTs (see figure). The resulting novel carbon hybrid material serves as stable anode in lithium batteries during 120 charge/discharge cycles. This work provides a simple and efficient way of converting conventional CNTs into functional carbon materials with an outstandingly high volumetric storage density.

引用

页码：1450 / +

页数：7

共 22 条

[1] Self-assembled vanadium pentoxide (V2O5) hollow microspheres from nanorods and their application in lithium-ion batteries [J].

Cao, AM ;

Hu, JS ;

Liang, HP ;

Wan, LJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (28) :4391-4395

[2] Carbon nanotubule membranes for electrochemical energy storage and production [J].

Che, GL ;

Lakshmi, BB ;

Fisher, ER ;

Martin, CR .

NATURE, 1998, 393 (6683) :346-349

[3] MECHANISMS FOR LITHIUM INSERTION IN CARBONACEOUS MATERIALS [J].

DAHN, JR ;

ZHENG, T ;

LIU, YH ;

XUE, JS .

SCIENCE, 1995, 270 (5236) :590-593

[4] Recent development of carbon materials for Li ion batteries [J].

Endo, M ;

Kim, C ;

Nishimura, K ;

Fujino, T ;

Miyashita, K .

CARBON, 2000, 38 (02) :183-197

[5] HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].

IIJIMA, S .

NATURE, 1991, 354 (6348) :56-58

[6] The electroemission of endo-fullerenes from a nanotube [J].

Kang, JW ;

Hwang, HJ .

NANOTECHNOLOGY, 2004, 15 (12) :1825-1830

[7] In situ Raman study on single- and double-walled carbon nanotubes as a function of lithium insertion [J].

Kim, YA ;

Kojima, M ;

Muramatsu, H ;

Umemoto, S ;

Watanabe, T ;

Yoshida, K ;

Sato, K ;

Ikeda, T ;

Hayashi, T ;

Endo, M ;

Terrones, M ;

Dresselhaus, MS .

SMALL, 2006, 2 (05) :667-676

[8] Carbon "peapods" - a new tunable nanoscale graphitic structure (Review) [J].

Krive, I. V. ;

Shekhter, R. I. ;

Jonson, M. .

LOW TEMPERATURE PHYSICS, 2006, 32 (10) :887-905

[9] Nanoionics: ion transport and electrochemical storage in confined systems [J].

Maier, J .

NATURE MATERIALS, 2005, 4 (11) :805-815

[10] High-energy, rechargeable Li-ion battery based on carbon nanotube technology [J].

Morris, RS ;

Dixon, BG ;

Gennett, T ;

Raffaelle, R ;

Heben, MJ .

JOURNAL OF POWER SOURCES, 2004, 138 (1-2) :277-280

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