Layered double hydroxides as a suitable substrate to improve the efficiency of Zn anode in neutral pH Zn-ion batteries

被引:73
作者
Gonzalez, M. A. [1 ]
Trocoli, R. [2 ]
Pavlovic, I. [1 ]
Barriga, C. [1 ]
La Mantia, F. [2 ,3 ]
机构
[1] Univ Cordoba, IUIQFN, Dept Quim Inorgan & Ingn Quim, E-14071 Cordoba, Spain
[2] Ruhr Univ Bochum, Zentrum Elektrochem CES, Semicond & Energy Convers, D-44801 Bochum, Germany
[3] Univ Bremen, Energiespeicher & Energiewandlersyst, D-28359 Bremen, Germany
关键词
Zinc-ion battery; Aqueous battery; Layered double hydroxides; Energy storage; AQUEOUS RECHARGEABLE BATTERY; ZINC; CATHODE; ELECTRODEPOSITION; STORAGE; CD(II); PB(II);
D O I
10.1016/j.elecom.2016.04.006
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
070208 [无线电物理];
摘要
Recently, neutral pH zinc-ion batteries (ZIBs) have received an increasing attention as a low cost and eco-friendly alternative to lithium-ion batteries. At variance with previous publications, we focused on the improvement of the zinc negative electrode in this work. By addition of layered double hydroxides to the preparation of the negative electrode, it was possible to increase the efficiency of zinc electro-deposition from 85% to 98%. This improvement was related to the elimination of a potential drop during the Zn2+ reduction step, avoiding the formation of H-2 at the beginning of the discharging step. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 4
页数:4
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