The Wittig reaction as a key step in the preparation of triangular ligands for the self-assembly of molecular M4L4 tetrahedra

被引:9
作者
Albrecht, Markus [1 ]
Burk, Simon [1 ]
Weis, Patrick [2 ]
Schalley, Christoph A. [3 ]
Kogej, Michael [3 ]
机构
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany
[2] Univ Karlsruhe, Inst Phys Chem, D-76128 Karlsruhe, Germany
[3] FU Berlin, Inst Chem & Biochem, D-14195 Karlsruhe, Germany
来源
SYNTHESIS-STUTTGART | 2007年 / 23期
基金
加拿大自然科学与工程研究理事会;
关键词
Wittig reaction; catechol; ligands; self-assembly; tetrahedra;
D O I
10.1055/s-2007-990826
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Triangular ligands based on a central C-3-symmetric backbone, ethylene linkages, and catechol ligand units, are prepared by a Wittig approach. The ligands form, in metal-directed self-assembly processes, tetrahedral coordination compounds of the composition M4L4.
引用
收藏
页码:3736 / 3740
页数:5
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