A conjugate addition of arylboronic acids to α,β-unsaturated carbonyl compounds catalyzed by 2β-CD-[Rh(OH)(cod)]2 or [RhCl(cod)]2 in a single aqueous medium

被引：54

作者：

Itooka, R ^{[1
]}

Iguchi, Y ^{[1
]}

Miyaura, N ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Engn, Div Mol Chem, Sapporo, Hokkaido 0608628, Japan

来源：

CHEMISTRY LETTERS | 2001年 / 07期

关键词：

D O I：

10.1246/cl.2001.722

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The rhodium-catalyzed conjugate addition of tolylboronic acid to alpha,beta -unsaturated ketones, esters or amides was carried out in water. [RhCl(cod)](2) and 2 beta -cyclodextrin-[Rh(OH)(cod)](2) complexes were found to catalyze the reaction efficiently in a single aqueous medium.

引用

页码：722 / 723

页数：2

共 12 条

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