Rhodium-catalyzed conjugate addition of aryl- or 1-alkenylboronic acids to enones

被引：515

作者：

Sakai, M ^{[1
]}

Hayashi, H ^{[1
]}

Miyaura, N ^{[1
]}

机构：

[1] HOKKAIDO UNIV,GRAD SCH ENGN,DIV MOL CHEM,SAPPORO,HOKKAIDO 060,JAPAN

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 20期

关键词：

D O I：

10.1021/om9705113

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The rhodium(I)-catalyzed conjugate addition. of aryl- or 1-alkenylboronic acids to enones was carried out in high yields at 50 degrees C in an aqueous solvent. A combination of(acac)Rh(CO)(2) and dppb was recognized to be highly effective for the addition to acyclic and cyclic enones.

引用

页码：4229 / 4231

页数：3

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