Electrochemical oxidation behavior of nitrite on a chitosan-carboxylated multiwall carbon nanotube modified electrode

被引:187
作者
Jiang, LY
Wang, RX
Li, XM
Jiang, LP
Lu, GH [1 ]
机构
[1] Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China
[2] Chizhou Teachers Coll, Dept Chem, Guichi 247000, Peoples R China
[3] Dezhou Coll, Dept Chem, Dezhou 253023, Peoples R China
关键词
chitosan; nitrite; multiwall carbon nanotube; electrochemistry; cyclic voltammetry;
D O I
10.1016/j.elecom.2005.04.009
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A novel chitosan-carboxylated multiwall carbon nanotube modified glassy carbon electrode (MC/GCE) was developed to investigate the oxidation behavior of nitrite using cyclic voltammetry and differential pulse voltammetry modes. The electrochemical mechanism of the MC/GCE towards nitrite was discussed. The MC/GCE exhibited fast response towards nitrite with a detection limit of 1 x 10(-7) Mol l(-1) and a linear range of 5 x 10(-7)-1 x 10(-4) Mol l(-1). The possible interference from several common ions was tested. The proposed method was successfully applied in the detection of nitrite in real samples. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:597 / 601
页数:5
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