Strategies for fabrication of hydrogen peroxide sensors based on electrostatic self-assembly (ESA) method

被引:22
作者
Del Villar, I
Matias, IR [1 ]
Arregui, FJ
Echeverría, J
Claus, RO
机构
[1] Univ Publ Navarra, Dept Ingn Elect & Elect, Pamplona 310006, Spain
[2] Aplicada Univ Publ Navarra, Dept Quim, Pamplona 31006, Spain
[3] Virginia Polytech Inst & State Univ, Bradley Dept Elect & Comp Engn, Fiber & Electro Opt Res Ctr, Blacksburg, VA 24061 USA
关键词
electrostatic self-assembly; hydrogen peroxide; optical fiber sensor; Prussian Blue;
D O I
10.1016/j.snb.2004.10.054
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
An optical fiber sensor has been fabricated for detection of 5 mu M-0.1 mM concentrations of hydrogen peroxide with a linear response. The deposition method used is electrostatic self-assembly (ESA) of polymer cationic and anionic layers. Prussian Blue (PB) has been included in the polycation layers. The optical fiber sensor is included in a reflection setup, where the measuring technique is based on the slope of the optical reflected power change caused by oxidation of Prussian White (PW) to Prussian Blue. The sensor recovers after immersion in a reductive agent and is immune against a variety of components. Measurement of hydrogen peroxide has been proved successfully in a wide range pHs between 3 and 9. Some techniques have been applied in order to avoid the lost of indicator. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:751 / 757
页数:7
相关论文
共 27 条
[1]   Optical fiber humidity sensor using a nano Fabry-Perot cavity formed by the ionic self-assembly method [J].
Arregui, FJ ;
Liu, YJ ;
Matias, IR ;
Claus, RO .
SENSORS AND ACTUATORS B-CHEMICAL, 1999, 59 (01) :54-59
[2]   Optical fiber nanometer-scale Fabry-Perot interferometer formed by the ionic self-assembly monolayer process [J].
Arregui, FJ ;
Matias, IR ;
Liu, YJ ;
Lenahan, KM ;
Claus, RO .
OPTICS LETTERS, 1999, 24 (09) :596-598
[3]  
ARREGUI FJ, 2003, P 2 IEEE SENS C
[4]   Application of iron-tetrasulfonatophthalocyanine as a new mimetic peroxidase in the determination of hydrogen peroxide with p-hydroxyphenylpropionic acid as a substrate [J].
Chen, QY ;
Li, DH ;
Zhu, QZ ;
Zheng, H ;
Xu, JG .
ANALYTICA CHIMICA ACTA, 1999, 381 (2-3) :175-182
[5]   Study of tetra-substituted amino aluminum phthalocyanine as a new red-region substrate for the fluorometric determination of peroxidase and hydrogen peroxide [J].
Chen, XL ;
Li, DH ;
Yang, HH ;
Zhu, QZ ;
Zheng, H ;
Xu, JG .
ANALYTICA CHIMICA ACTA, 2001, 434 (01) :51-58
[6]   Methods of loading and releasing low molecular weight cationic molecules in weak polyelectrolyte multilayer films [J].
Chung, AJ ;
Rubner, MF .
LANGMUIR, 2002, 18 (04) :1176-1183
[7]   Fuzzy nanoassemblies: Toward layered polymeric multicomposites [J].
Decher, G .
SCIENCE, 1997, 277 (5330) :1232-1237
[8]   Development of multilayer fluorescent thin film chemical sensors using electrostatic self-assembly [J].
Grant, PS ;
McShane, MJ .
IEEE SENSORS JOURNAL, 2003, 3 (02) :139-146
[9]   Spectrophotometric determination of hydrogen peroxide and glucose based on hemin peroxidase-like catalyzed oxidation of bromopyrogallol red [J].
Guo, ZX ;
Shen, HX ;
Li, L .
MIKROCHIMICA ACTA, 1999, 131 (3-4) :171-176
[10]  
*INT STAND ORG, 1996, 7157 ISODIS