Synthesis of novel diphosphines from D-(+)-glucose.: Use in asymmetric hydrogenation

被引：19

作者：

Diéguez, M

Pàmies, O

Ruiz, A

Castillón, S

Claver, C

机构：

[1] Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43005, Spain

[2] Univ Rovira & Virgili, Dept Quim Analit & Organ, Tarragona 43005, Spain

来源：

TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 23期

关键词：

D O I：

10.1016/S0957-4166(00)00440-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new family of bidentate diphosphine ligands which contain a glucofuranoside as a simple but highly effective chiral backbone are reported. These ligands are prepared in a few steps from readily available D-(+)-glucose. These new ligands have been applied to the rhodium-catalysed hydrogenation of cl,p-unsaturated carboxylic acid derivatives under very mild reaction conditions, with enantiomeric excesses of up to 98%. (C) 2001 Elsevier Science Ltd. An rights reserved.

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页码：4701 / 4708

页数：8

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