Enzyme catalysis in ionic liquids:: lipase catalysed kinetic resolution of 1-phenylethanol with improved enantioselectivity

被引：356

作者：

Schöfer, SH

Kaftzik, N

Wasserscheid, P

Kragl, U ^{[1
]}

机构：

[1] Univ Rostock, Dept Chem, D-18051 Rostock, Germany

[2] Rhein Westfal TH Aachen, Inst Tech Chem & Makromol Chem, D-52066 Aachen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 05期

关键词：

D O I：

10.1039/b009389k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lipases show good activity and, in some cases, improved enantioselectivity when employed in pure ionic liquids for dynamic kinetic resolution of 1-phenylethanol by transesterification.

引用

页码：425 / 426

页数：2

共 20 条

[1]

BLINKORSKY AM, 1999, J AM CHEM SOC, V116, P2697

[2]

Bornscheuer UT, 2006, HYDROLASES IN ORGANIC SYNTHESIS: REGIO- AND STEREOSELECTIVE BIOTRANSFORMATIONS, 2ND EDITION, P1

[3] Biotransformation in organic media by enzymes and whole cells [J].

Cabral, JMS ;

Aires-Barros, MR ;

Pinheiro, H ;

Prazeres, DMF .

JOURNAL OF BIOTECHNOLOGY, 1997, 59 (1-2) :133-143

[4]

CARREA G, 2000, ANGEW CHEM, V112, P2312

[5]

Cull SG, 2000, BIOTECHNOL BIOENG, V69, P227

[6] Enzymatic catalysis of formation of Z-aspartame in ionic liquid -: An alternative to enzymatic catalysis in organic solvents [J].

Erbeldinger, M ;

Mesiano, AJ ;

Russell, AJ .

BIOTECHNOLOGY PROGRESS, 2000, 16 (06) :1129-1131

[7]

Faber K., 2000, Biotransformations in Organic Chemistry, V4th

[8]

Hartmann T., 2000, STEREOSELECTIVE BIOC, P799

[9]

KAFTZIK N, UNPUB ANGEW CHEM INT

[10]

KILBANOV AM, 1986, CHEMTECH, V16, P354

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