Fluorescence micro(spectro)scopy as a tool to study catalytic materials in action

被引:117
作者
De Cremer, Gert [1 ]
Sels, Bert F. [1 ]
De Vos, Dirk E. [1 ]
Hofkens, Johan [2 ]
Roeffaers, Maarten B. J. [1 ,2 ]
机构
[1] Katholieke Univ Leuven, Dept Mol & Microbial Syst, B-3001 Heverlee, Belgium
[2] Katholieke Univ Leuven, Lab Photochem & Spect, Dept Chem, B-3001 Heverlee, Belgium
关键词
SINGLE-MOLECULE; ZEOLITE CRYSTALS; INTERGROWTH STRUCTURE; H-ZSM-5; CRYSTALS; ZSM-5; X-RAY; DIFFUSION; TIME; SPACE; MICROSCOPY;
D O I
10.1039/c0cs00047g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Following its widespread use in biomedical research, fluorescence microscopy has recently been introduced in the catalysis field to study chemocatalytic processes with a high spatiotemporal resolution, a unique sensitivity down to the single molecule level and this under in situ conditions. This tutorial review is structured around the length scales that are currently accessible in fluorescence microscopy and discusses the different conceptual approaches that have been developed to study molecular concentration and dynamics like diffusion and catalytic conversion at these micron and sub-micron levels.
引用
收藏
页码:4703 / 4717
页数:15
相关论文
共 84 条
[1]   Towards direct monitoring of discrete events in a catalytic cycle at the single molecule level [J].
Ameloot, Rob ;
Roeffaers, Maarten ;
Baruah, Mukulesh ;
De Cremer, Gert ;
Sels, Bert ;
De Vos, Dirk ;
Hofkens, Johan .
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2009, 8 (04) :453-456
[2]   Probing the transport of paramagnetic complexes inside catalyst bodies in a quantitative manner by magnetic resonance imaging [J].
Bergwerff, Jaap A. ;
Lysova, Anna A. ;
Alonso, Leticia Espinosa ;
Koptyug, Igor V. ;
Weckhuysen, Bert M. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (38) :7224-7227
[3]   Hexagonal microlasers based on organic dyes in nanoporous crystals [J].
Braun, I ;
Ihlein, G ;
Laeri, F ;
Nöckel, JU ;
Schulz-Ekloff, G ;
Schüth, F ;
Vietze, U ;
Weiss, Ö ;
Wöhrle, D .
APPLIED PHYSICS B-LASERS AND OPTICS, 2000, 70 (03) :335-343
[4]   Time, space, and spectrally resolved studies on J-aggregate interactions in zeolite L nanochannels [J].
Busby, Michael ;
Blum, Christian ;
Tibben, Marc ;
Fibikar, Sandra ;
Calzaferri, Gion ;
Subramaniam, Vinod ;
De Cola, Luisa .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (33) :10970-10976
[5]   Surface-enhanced Raman scattering [J].
Campion, A ;
Kambhampati, P .
CHEMICAL SOCIETY REVIEWS, 1998, 27 (04) :241-250
[6]   Toward the single-molecule investigation of organometallic reaction mechanisms: Single-molecule imaging of fluorophore-tagged palladium(II) complexes [J].
Canham, Stephen M. ;
Bass, Jonathan Y. ;
Navarro, Oscar ;
Lim, Sung-Gon ;
Das, Neeladri ;
Blum, Suzanne A. .
ORGANOMETALLICS, 2008, 27 (10) :2172-2175
[7]   SELECTIVE SORPTION UPTAKE KINETICS OF N-HEXANE ON ZSM-5 - A NEW METHOD FOR MEASURING ANISOTROPIC DIFFUSIVITIES [J].
CARO, J ;
NOACK, M ;
RICHTERMENDAU, J ;
MARLOW, F ;
PETERSOHN, D ;
GRIEPENTROG, M ;
KORNATOWSKI, J .
JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (51) :13685-13690
[8]   Quantitative comparison of algorithms for tracking single fluorescent particles [J].
Cheezum, MK ;
Walker, WF ;
Guilford, WH .
BIOPHYSICAL JOURNAL, 2001, 81 (04) :2378-2388
[9]   Single-nanoparticle catalysis at single-turnover resolution [J].
Chen, Peng ;
Xu, Weilin ;
Zhou, Xiaochun ;
Panda, Debashis ;
Kalininskiy, Aleksandr .
CHEMICAL PHYSICS LETTERS, 2009, 470 (4-6) :151-157
[10]   Mapping the Distribution of an Individual Chromophore Interacting with Silica-Based Nanomaterials [J].
Cohen, Boiko ;
Sanchez, Felix ;
Douhal, Abderrazzak .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (15) :5507-5514