Disrotatory and conrotatory transition structures for the Fe(CO)3-templated rearrangement of methylenecyclopropane to trimethylenemethane

被引：19

作者：

Tantillo, DJ ^{[1
]}

Carpenter, BK ^{[1
]}

Hoffmann, R ^{[1
]}

机构：

[1] Cornell Univ, Dept Chem & Biol Chem, Ithaca, NY 14853 USA

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 22期

关键词：

D O I：

10.1021/om010579p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hybrid HF-DFT calculations were used to compute the structures and relative energetics of competing disrotatory and conrotatory transition states for ring-opening of Fe(CO)(3)-complexed methylenecyclopropanes.

引用

页码：4562 / 4564

页数：3

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