BINAS - Synthesis and use of a new ligand for propylene hydroformylation

被引：30

作者：

Bahrmann, H

Bergrath, K

Kleiner, HJ

Lappe, P

Naumann, C

Peters, D

Regnat, D

机构：

[1] HOECHST AG,CENT RES,D-65926 FRANKFURT,GERMANY

[2] HOECHST AG,RES & DEV GLOBAL BASIC CHEM,D-46128 OBERHAUSEN,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 520卷 / 1-2期

关键词：

BINAS; phosphorus ligands; propylene hydroformylation;

D O I：

10.1016/0022-328X(96)06268-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

BINAS is a new, very efficient ligand for propylene hydroformylation. BINAS is made by me sulfonation of NAPHOS. Different synthetic routes to NAPHOS are discussed. A new two step synthesis starting from 2,2'-bis(bromomethyl)-1,1'-binaphthyl is described.

引用

页码：97 / 100

页数：4

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