Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

被引：270

作者：

Hu, XL ^{[1
]}

Cossairt, BM ^{[1
]}

Brunschwig, BS ^{[1
]}

Lewis, NS ^{[1
]}

Peters, JC ^{[1
]}

机构：

[1] CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USA

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 37期

关键词：

D O I：

10.1039/b509188h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H-2 at potentials as positive as -0.28 V vs. SCE.

引用

页码：4723 / 4725

页数：3

共 29 条

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