Conducting polymer gel: formation of a novel semi-IPN from polyaniline and crosslinked poly (2-acrylamido-2-methyl propanesulphonicacid)

In the present article, a simple two-step technique for synthesis of electrically conducting hydrogel is described. The synthesized hydrogel is originally a semi-interpenetrating polymer network (IPN) in which conducting polyaniline (linear) is entrapped within a crosslinked polyelectrolyte gel viz. poly(2-acrylamido-2-methyl propane sulphonic acid) (PAMPS). A conventional photo-polymerization technique was followed for synthesis of the PAMPS gel while aniline is in situ polymerized within the gel, giving rise to the desired semi-IPN. For comparison, a neutral gel based semi-IPN PAn-PAAm (polyaniline-polyacrylamide) was also prepared following the similar route. PAn imparts appreciable electrical conductivity to both PAMPS and PAAm based gels without hampering their existing properties that indicates the success of the work. Synthesis of the gel was studied in detail and different experimental conditions were optimized. Different physical properties of the gel viz. its degree of swelling, electrical conductivity, mechanical strength, etc were also studied. The resultant semi-IPN or the composite hydrogel was found to possess appreciable electrical conductivity, good swellability and mechanical strength. The electrodriven volume contraction of the composite gel was found to occur at sufficiently lower voltage compared to the pure PAMPS gel, which indicates its promising application aspect in fabrication of chemomechanical devices. (c) 2005 Elsevier Ltd. All rights reserved.