Common and less-common coordination modes of the typical chelating and heteroaromatic ligands

被引：61

作者：

Garnovskii, AD

Sadimenko, AP ^{[1
]}

Sadimenko, MI

Garnovskii, DA

机构：

[1] Univ Ft Hare, ZA-5701 Alice, South Africa

[2] Rostov State Univ, Inst Phys & Organ Chem, Rostov Na Donu 344090, Russia

来源：

COORDINATION CHEMISTRY REVIEWS | 1998年 / 173卷

关键词：

coordination mode; competitive coordination; diketones; azomethines; mercaptoazoles; mercaptoazines; heteroaromatic ligands;

D O I：

10.1016/S0010-8545(98)00084-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Data on the different modes of bonding the metals to the most widely spread chelating [beta-diketones, o-oxyazomethines, o-oxy(mercapto) derivatives of azoles and azines] and heteroaromatic ligands are generalized and systematized. It is shown that, besides the common beta-diketonates, aldiminates, phenolates and mercaptophenolates structures, these complex compounds exhibit less-common modes of coordination. Five- and six-membered heterocycles form sigma- as well as pi-complexes. (C) 1998 Elsevier Science S.A.

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页码：31 / 77

页数：47

相关论文

共 456 条

[71]

Bohm D., 1995, ANGEW CHEM, V107, P251

[72] REACTIONS OF C-IMIDAZOLYLLITHIUM DERIVATIVES WITH GROUP-IB COMPOUNDS - TRIS[MU-(1-ALKYLIMIDAZOLATO-N3,C2)]TRI-GOLD(I) AND TRI-SILVER(I) - CRYSTAL-STRUCTURE OF BIS(1-BENZYLIMIDAZOLIN-2-YLIDEN)GOLD(I) CHLORIDE [J].

BONATI, F ;

BURINI, A ;

PIETRONI, BR ;

BOVIO, B .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 375 (01) :147-160

[73] N-SUBSTITUTED IMIDAZOLE DERIVATIVES OF RHODIUM(I) AND IRIDIUM(I) - CRYSTAL-STRUCTURE OF THE HEAD-TO-HEAD DINUCLEAR COMPOUND [IR-2(MU-N-BENZYLIMIDAZOLATO-N-3,C-2)(2)(CO)(4)] [J].

BONATI, F ;

ORO, LA ;

PINILLOS, MT ;

TEJEL, C .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 465 (1-2) :267-274

[74] REACTIONS OF SYMMETRIC C-IMIDAZOLYLGOLD(I) LEADING TO AU(I) CARBENE COMPLEXES OR MIXED-VALENCE OR AU(III) IMIDAZOLYL DERIVATIVES - CRYSTAL-STRUCTURE OF [1-BENZYL-3-(CARBOETHOXY)IMIDAZOLIN-2-YLIDEN]CHLOROGOLD(I) [J].

BONATI, F ;

BURINI, A ;

PIETRONI, BR ;

BOVIO, B .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 408 (02) :271-280

[75] REACTIONS OF (TERTIARY PHOSPHINE)GOLD(I) SUBSTITUTED IMIDAZOLES OR PYRAZOLONES WITH ACIDIC REAGENTS - PROTONATION, AZOLE DISPLACEMENT, AND ADDUCT FORMATION - CRYSTAL-STRUCTURE DETERMINATION OF THE ADDUCT 1-METHYL-2-(CYCLOHEXYLPHOSPHINEGOLDTHIOLATO)IMIDAZOLE.2BENZIMIDAZOLE [J].

BONATI, F ;

BURINI, A ;

PIETRONI, BR ;

GIORGINI, E ;

BOVIO, B .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 344 (01) :119-135

[76] A AU-197 MOSSBAUER STUDY OF REACTION-PRODUCTS OF TRIMERIC 1-BENZYL-2-GOLD(I)-IMIDAZOLE LEADING TO AU(I) CARBENE OR AU(I) IMIDAZOLINE COMPLEXES AND TRINUCLEAR AU(III) IMIDAZOLYL DERIVATIVES - X-RAY CRYSTAL-STRUCTURE OF [((MU-1-BENZYLIMIDAZOLATO-N3,C2)AU)3I2] [J].

BOVIO, B ;

CALOGERO, S ;

WAGNER, FE ;

BURINI, A ;

PIETRONI, BR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 470 (1-2) :275-283

[77] CARBONYLIRON COMPLEXES OF A 1,3-DIHYDRO-1,3-DIBORAPENTAFULVENE DERIVATIVE [J].

BRODT, G ;

SIEBERT, W .

CHEMISCHE BERICHTE, 1989, 122 (04) :633-634

[78] CLUSTER CHEMISTRY .48. SOME REACTIONS OF RU3(CO)12 WITH NITROGEN-HETEROCYCLES - X-RAY CRYSTAL-STRUCTURES OF RU3(MU-CO)2(CO)8(BIPY) AND RU3(MU-H)(MU-N2C3H(CF3)2-3,5)(CO)10 [J].

BRUCE, MI ;

HUMPHREY, MG ;

SNOW, MR ;

TIEKINK, ERT ;

WALLIS, RC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 314 (03) :311-322

[79]

BUCKINGHAM DA, 1987, COMPREHENSIVE COORDI, V4, P636

[80] SCHIFF-BASE COMPLEXES OF CALCIUM - CRYSTAL-STRUCTURE ANALYSIS OF DINITRATO[N,N'-PROPANE-1,3-DIYLBIS(SALICYLIDENEIMINE)]CALCIUM(II) AND THE SPECTROSCOPIC PROPERTIES OF SOME RELATED COMPLEXES [J].

BULLOCK, JI ;

LADD, MFC ;

POVEY, DC ;

TAJMIRRIAHI, HA .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (SEP) :2013-2020

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