Detection of an individual single-wall carbon nanotube by tip-enhanced near-field Raman spectroscopy

A tip-enhanced near-field Raman microscope has been applied to the detection of an individual single-wall carbon nanotube (SWNT). The detected information is a color (Raman-shift) image of molecular distribution without having to resort to staining non-fluorescent molecules of interest. In addition to nanometric-sensing and -imaging capability, local field-enhancement of the metallic tip has been utilized to detect a weak Raman scattering from nanometer region, which cannot be observed by conventional micro-Raman configuration (far-field Raman). The experimental results are shown with analysis of distinct vibration modes of both radial breathing mode and G-band. (C) 2003 Elsevier Science B.V. All rights reserved.