Reflections on routes to enantioselective solid catalysts

被引：77

作者：

Davis, ME ^{[1
]}

机构：

[1] CALTECH, Pasadena, CA 91125 USA

来源：

TOPICS IN CATALYSIS | 2003年 / 25卷 / 1-4期

关键词：

enantioselective solids; imprinting; zeolites; chirality; inorganic solids;

D O I：

10.1023/B:TOCA.0000003093.74240.23

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The intellectual and practical challenges of preparing enantioselective solids are discussed and two routes to the possible assembly of chiral inorganic structures highlighted. These synthesis methods are the imprinting of amorphous structures and the crystallization of chiral, crystalline, and microporous materials. For both types of solids, there is the potential to create chirality within the structure that may allow for long-term, robust use in catalytic reactions without significant loss of enantioselectivity.

引用

收藏

页码：3 / 7

页数：5

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