Stable organoboron polymers prepared by hydroboration polymerization of dienes with tripylborane

被引：6

作者：

Miyata, M ^{[1
]}

Meyer, F ^{[1
]}

Chujo, Y ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

POLYMER BULLETIN | 2001年 / 46卷 / 01期

关键词：

D O I：

10.1007/s002890170084

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Hydroboration polymerization between diene monomers and 2,4,6-triisopropylphenylborane (tripylborane) gave organoboron main-chain polymers. The polymerization was carried out by adding a diene monomer to a THF solution of tripylborane at room temperature under nitrogen. The obtained polymers were found to be more stable compared with the polymers prepared from thexylborane or mesitylborane.

引用

页码：23 / 28

页数：6

共 13 条

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