Water-soluble rhodium/phosphonate-phosphine catalysts for hydroformylation

被引：29

作者：

Bischoff, S ^{[1
]}

Kant, M ^{[1
]}

机构：

[1] Inst Appl Chem, D-12489 Berlin, Germany

来源：

CATALYSIS TODAY | 2001年 / 66卷 / 2-4期

关键词：

rhodium; hydroformylation; water-soluble catalyst; aqueous catalyst; biphasic; phosphonate-phosphine;

D O I：

10.1016/S0920-5861(00)00647-7

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

We have developed new and efficient routes to modify phosphines with phosphonic acid groups. Phosphonate-phosphines showed high solubilities in water and were used to immobilise rhodium catalysts in the aqueous phase of biphasic systems. In the two-phase hydroformylation of propylene, some of the novel catalysts showed activities and regioselectivities similar to those of Rh/TPPTS. Amphiphilic Rh/phosphonate-phosphine catalysts were found widely superior to Rh/TPPTS in the hydroformylation of 1-octene. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：183 / 189

页数：7

共 31 条

[1] BACH H, 1986, Patent No. 3616057
[2] PROGRESS IN HYDROFORMYLATION AND CARBONYLATION
BELLER, M
CORNILS, B
FROHNING, CD
KOHLPAINTNER, CW
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 104 (01) : 17 - 85
[3] Soluble and supported carbonylation catalysts derived from rhodium-phosphonate-phosphane complexes
Bischoff, S
Weigt, A
Miessner, H
Lucke, B
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 107 (1-3) : 339 - 346
[4] Supported phosphonate-phosphane complexes for vapour-phase carbonylation
Bischoff, S
Weigt, A
Kant, M
Schulke, U
Lucke, B
[J]. CATALYSIS TODAY, 1997, 36 (03) : 273 - 284
[5] Micellar effect in high olefin hydroformylation catalyzed by water-soluble rhodium complex
Chen, H
Li, YZ
Chen, JR
Cheng, PM
He, YE
Li, HJ
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 149 (1-2) : 1 - 6
[6] Bulk and fine chemicals via aqueous biphasic catalysis
Cornils, B
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 143 (1-3) : 1 - 10
[7] Industrial aspects of aqueous catalysis
Cornils, B
Herrmann, WA
Eckl, RW
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 116 (1-2) : 27 - 33
[8] Cornils B., 1996, APPL HOMOGENEOUS CAT, V2
[9] SYNTHESIS AND CHARACTERIZATION OF NEW WATER-SOLUBLE TERTIARY PHOSPHINES HAVING TERMINALLY SUBSTITUTED ALKYLENE SULFONATE OR ALKYLENE PHOSPHONATE CHAINS
GANGULY, S
MAGUE, JT
ROUNDHILL, DM
[J]. INORGANIC CHEMISTRY, 1992, 31 (17) : 3500 - 3501
[10] GERMANAUD L, 1988, B SOC CHIM FR, P699

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