Hydrotris(7-tert-butylindazol-2-yl)borate: A super-hindered homoscorpionate ligand

被引：21

作者：

Rheingold, AL ^{[1
]}

LiableSands, LM ^{[1
]}

Yap, GPA ^{[1
]}

Trofimenko, S ^{[1
]}

机构：

[1] DUPONT CO INC,EXPT STN,WILMINGTON,DE 19880

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 10期

关键词：

D O I：

10.1039/cc9960001233

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The super-hindered ligand hydrotris(7-tert-butylindazol-2-yl)borate is synthesized and shown to undergo rearrangement during the formation of a tetrahedral cobalt(II) complex.

引用

页码：1233 / 1234

页数：2

共 14 条

[1] HYDROTRIS(3-NEOPENTYLPYRAZOL-1-YL)BORATES - A NEW TYPE OF STERICALLY HINDERED POLY(PYRAZOLYL)BORATE [J].

CALABRESE, JC ;

TROFIMENKO, S .

INORGANIC CHEMISTRY, 1992, 31 (23) :4810-4814

[2] TRIS(PYRAZOLYL)HYDROBORATOZINC ALKYL DERIVATIVES - DIRECT COMPARISON OF THE REACTIVITY OF ZN-C AND MG-C BONDS [J].

GORRELL, IB ;

LOONEY, A ;

PARKIN, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (03) :220-222

[3] SYNTHESIS, STRUCTURE, AND REACTIVITY OF (ETA(3)-HB(3-BUTPZ)3)BECH3, A TERMINAL BERYLLIUM ALKYL COMPLEX SUPPORTED BY TRIS(3-TERT-BUTYLPYRAZOLYL)HYDROBORATO LIGATION [J].

HAN, R ;

PARKIN, G .

INORGANIC CHEMISTRY, 1993, 32 (22) :4968-4970

[4] (TRIS(PYRAZOLYL)HYDROBORATO)MAGNESIUM AND (TRIS(PYRAZOLYL)HYDROBORATO-ALUMINUM ALKYL DERIVATIVES - ALKYL EXCHANGE WITH METHYL-IODIDE AND ENOLATE FORMATION WITH ACETONE [J].

HAN, R ;

LOONEY, A ;

PARKIN, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (18) :7276-7278

[5] POLY(BENZOTRIAZOLYL)BORATES .1. LIGAND SYNTHESIS AND CHARACTERIZATION [J].

LALOR, FJ ;

MILLER, SM ;

GARVEY, N .

POLYHEDRON, 1990, 9 (01) :63-68

[6] TRIS(PYRAZOLYL)HYDROBORATO COMPLEXES OF CADMIUM - A BIDENTATE NITRATE DERIVATIVE AND ITS RELEVANCE TO CARBONIC-ANHYDRASE ACTIVITY [J].

LOONEY, A ;

SALEH, A ;

ZHANG, YH ;

PARKIN, G .

INORGANIC CHEMISTRY, 1994, 33 (06) :1158-1164

[7] REACTIVITY OF INDAZOLES AND BENZOTRIAZOLE TOWARDS N-METHYLATION AND ANALYSIS OF H-1 NUCLEAR MAGNETIC-RESONANCE SPECTRA OF INDAZOLES AND BENZOTRIAZOLES [J].

PALMER, MH ;

FINDLAY, RH ;

KENNEDY, SMF ;

MCINTYRE, PS .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1975, (15) :1695-1700

[8] DO POLY(INDAZOLYL)BORATES HAVE ABNORMAL REGIOCHEMISTRY [J].

RHEINGOLD, AL ;

YAP, G ;

TROFIMENKO, S .

INORGANIC CHEMISTRY, 1995, 34 (04) :759-760

[9] HOMOSCORPIONATE (TRIS(PYRAZOLYL)BORATE) LIGANDS CONTAINING TETHERED 3-PHENYL GROUPS [J].

RHEINGOLD, AL ;

OSTRANDER, RL ;

HAGGERTY, BS ;

TROFIMENKO, S .

INORGANIC CHEMISTRY, 1994, 33 (17) :3666-3676

[10] A NOVEL HOMOSCORPIONATE LIGAND AND ITS UNUSUAL BONDING IN A MOLYBDENUM COMPLEX [J].

RHEINGOLD, AL ;

HAGGERTY, BS ;

TROFIMENKO, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (17) :1973-1974

← 1 2 →