Diels-Alder reactions of the [60]fullerene - Functionalizing a carbon sphere with flexibly and with rigidly bound addends

被引：44

作者：

Krautler, B

Maynollo, J

机构：

[1] Institute of Organic Chemistry, University of Innsbruck

来源：

TETRAHEDRON | 1996年 / 52卷 / 14期

关键词：

D O I：

10.1016/0040-4020(96)00111-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The regioselective functionalization of the [60]fullerene (1) (buckminsterfullerene) by way of [4+2]-cycloaddition reactions (Diels-Alde reactions) has given synthetic access to exohedrally derivatized fullerenes, with either flexibly or rigidly bound addends. The binding of the addends to the central carbon sphere can be made effectively irreversible by subsequent addition reactions at their double bond. (C) 1996 Elsevier Science Ltd

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页码：5033 / 5042

页数：10

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