REACTION OF BUCKMINSTERFULLERENE WITH ORTHO-QUINODIMETHANE - A NEW ACCESS TO STABLE C60 DERIVATIVES

被引：240

作者：

BELIK, P ^{[1
]}

GUGEL, A ^{[1
]}

SPICKERMANN, J ^{[1
]}

MULLEN, K ^{[1
]}

机构：

[1] MAX PLANCK INST POLYMER RES,ACKERMANNWEG 10,W-6500 MAINZ,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 01期

关键词：

D O I：

10.1002/anie.199300781

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The stable diene adduct 1 can be prepared in(~)good yield when C60 is treated with o-quinodimethane in toluene. o-Quinodimethane is generated in situ from 1,2-bis(bromomethyl)benzene and KI in the presence of [18]crown-6 as phase-transfer catalyst. Adduct 1 was isolated after gel-permeation chromatography, and characterized by mass spectrometry and NMR spectroscopy; the sketch shows its geometry-optimized structure.(~)[GRAPHICS]

引用

页码：78 / 80

页数：3

共 28 条

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