Soluble manganese(IV); a new chemiluminescence reagent

被引：41

作者：

Barnett, NW ^{[1
]}

Hindson, BJ

Lewis, SW

Jones, P

Worsfold, PJ

机构：

[1] Deakin Univ, Sch Biol & Chem Sci, Ctr Chiral & Mol Technol, Geelong, Vic 3217, Australia

[2] Univ Plymouth, Dept Environm Sci, Plymouth Environm Res Ctr, Plymouth PL4 8AA, Devon, England

来源：

ANALYST | 2001年 / 126卷 / 10期

关键词：

D O I：

10.1039/b106492d

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The oxidations of twenty five organic and inorganic species, with solublised manganese(IV), were found to elicit analytically useful chemiluminescence with detection limits (3 x S/N) for Mn(II), Fe(II), morphine and codeine of 5 x 10(-8) M, 2.5 x 10(-7) M, 7.5 x 10(-8) M and 5 x 10(-8) M, respectively. Additionally, the corrected spectra from four different analytes gave wavelengths of maximum emission in the range from 733 nm up to 740 nm suggesting that all these chemiluminescence reactions shared a common emitting species.

引用

页码：1636 / 1639

页数：4

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