The selective catalytic oxidation of silanes to silanols with H2O2 activated by the Ti-beta zeolite

被引：40

作者：

Adam, W

Garcia, H

Mitchell, CM

Saha-Möller, CR

Weichold, O

机构：

[1] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany

[2] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, E-46071 Valencia, Spain

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 23期

关键词：

D O I：

10.1039/a807442i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ti-beta catalyses the oxidation of small- and medium-sized silanes to the corresponding silanols by aqueous (30%) H2O2 as oxygen donor with high conversions and excellent selectivity (no disiloxane).

引用

页码：2609 / 2610

页数：2

共 19 条

[1] Diastereoselective catalytic epoxidation of chiral allylic alcohols by the TS-1 and Ti-beta zeolites: Evidence for a hydrogen-bonded, peroxy-type loaded complex as oxidizing species
Adam, W
Corma, A
Reddy, TI
Renz, M
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (11) : 3631 - 3637
[2] O-ATOM INSERTION INTO SI-H BONDS BY DIOXIRANES - A STEREOSPECIFIC AND DIRECT CONVERSION OF SILANES INTO SILANOLS
ADAM, W
MELLO, R
CURCI, R
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (08): : 890 - 891
[3] ADAM W, UNPUB J AM CHEM SOC
[4] Oxidative transformations of organic compounds mediated by redox molecular sieves
Arends, IWCE
Sheldon, RA
Wallau, M
Schuchardt, U
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (11) : 1144 - 1163
[5] THE STATE OF TI IN TITANOALUMINOSILICATES ISOMORPHOUS WITH ZEOLITE-BETA
BLASCO, T
CAMBLOR, MA
CORMA, A
PEREZPARIENTE, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (25) : 11806 - 11813
[6] SYNTHESIS OF TITANOALUMINOSILICATES ISOMORPHOUS TO ZEOLITE BETA, ACTIVE AS OXIDATION CATALYSTS
CAMBLOR, MA
CORMA, A
PEREZPARIENTE, J
[J]. ZEOLITES, 1993, 13 (02): : 82 - 87
[7] SYNTHESIS OF A TITANIUMSILICOALUMINATE ISOMORPHOUS TO ZEOLITE-BETA AND ITS APPLICATION AS A CATALYST FOR THE SELECTIVE OXIDATION OF LARGE ORGANIC-MOLECULES
CAMBLOR, MA
CORMA, A
MARTINEZ, A
PEREZPARIENTE, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (08) : 589 - 590
[8] ACTIVITY OF TI-BETA CATALYST FOR THE SELECTIVE OXIDATION OF ALKENES AND ALKANES
CORMA, A
CAMBLOR, MA
ESTEVE, P
MARTINEZ, A
PEREZPARIENTE, J
[J]. JOURNAL OF CATALYSIS, 1994, 145 (01) : 151 - 158
[9] EGGER C, 1991, Z NATURFORSCH B, V46, P783
[10] Titanium containing molecular sieves as catalysts for selective oxidation reactions with hydrogen peroxide
Hoft, E
Kosslick, H
Fricke, R
Hamann, HJ
[J]. JOURNAL FUR PRAKTISCHE CHEMIE-CHEMIKER-ZEITUNG, 1996, 338 (01): : 1 - 15

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