Carbon nanotube-bonded graphene hybrid aerogels and their application to water purification

被引:80
作者
Lee, Byeongho [1 ]
Lee, Sangil [1 ]
Lee, Minwoo [2 ]
Jeong, Dae Hong [2 ]
Baek, Youngbin [3 ]
Yoon, Jeyong [3 ]
Kim, Yong Hyup [1 ]
机构
[1] Seoul Natl Univ, Sch Mech & Aerosp Engn, Seoul 151742, South Korea
[2] Seoul Natl Univ, Dept Chem Educ, Seoul 13742, South Korea
[3] Seoul Natl Univ, ICP, Sch Chem & Biol Engn, Seoul 151742, South Korea
基金
新加坡国家研究基金会;
关键词
PILLARED-GRAPHENE; HIGHLY EFFICIENT; REDUCED GRAPHENE; IN-SITU; ADSORPTION; OXIDE; DYES; NANOSTRUCTURE; SANDWICH; HYDROGEN;
D O I
10.1039/c5nr01018g
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
We present carbon nanotube (CNT)-bonded graphene hybrid aerogels that are prepared by growing CNTs on a graphene aerogel surface with nickel catalyst. The presence of bonded CNTs in the graphene aerogel results in vastly improved mechanical and electrical properties. A significant increase in specific surface area is also realized. The presence of the CNTs transforms the hybrid aerogels into a mesoporous material. The viscoelasticity of the hybrid aerogels is found to be invariant with respect to temperature over a range of between -150 degrees C and 450 degrees C. These characteristics along with the improved properties make the hybrid aerogels an entirely different class of material with applications in the fields of biotechnology and electrochemistry. The mesoporous nature of the material along with its high specific surface area also makes the hybrid aerogel attractive for application in water treatment. Both anionic and cationic dyes can be effectively removed from water by the hybrid aerogel. A number of organics and oils can be selectively separated from water by the hybrid aerogel. The hybrid aerogel is easy to handle and separate from water due to its magnetic nature, and can readily be recycled and reused.
引用
收藏
页码:6782 / 6789
页数:8
相关论文
共 40 条
[1]
Adsorption of Molecular Hydrogen in a Graphene-Carbon Nanotube System [J].
Arellano, J. S. .
JOURNAL OF NANO RESEARCH, 2009, 5 :201-211
[2]
Chen L, 2012, J MATER CHEM, V22, P22090, DOI [10.1039/c2jm34541, 10.1039/c2jm34541b]
[3]
Carbon nanotubes grown in situ on graphene nanosheets as superior anodes for Li-ion batteries [J].
Chen, Shuangqiang ;
Chen, Peng ;
Wang, Yong .
NANOSCALE, 2011, 3 (10) :4323-4329
[4]
Self-Assembly and Embedding of Nanoparticles by In Situ Reduced Graphene for Preparation of a 3D Graphene/Nanoparticle Aerogel [J].
Chen, Wufeng ;
Li, Sirong ;
Chen, Chunhua ;
Yan, Lifeng .
ADVANCED MATERIALS, 2011, 23 (47) :5679-+
[5]
Pillared Graphene: A New 3-D Network Nanostructure for Enhanced Hydrogen Storage [J].
Dimitrakakis, Georgios K. ;
Tylianakis, Emmanuel ;
Froudakis, George E. .
NANO LETTERS, 2008, 8 (10) :3166-3170
[6]
One-step growth of graphene-carbon nanotube hybrid materials by chemical vapor deposition [J].
Dong, Xiaochen ;
Li, Bing ;
Wei, Ang ;
Cao, Xiehong ;
Chan-Park, M. B. ;
Zhang, Hua ;
Li, Lain-Jong ;
Huang, Wei ;
Chen, Peng .
CARBON, 2011, 49 (09) :2944-2949
[7]
Bio-inspired surface-functionalization of graphene oxide for the adsorption of organic dyes and heavy metal ions with a superhigh capacity [J].
Dong, Zhihui ;
Wang, Dong ;
Liu, Xia ;
Pei, Xianfeng ;
Chen, Liwei ;
Jin, Jian .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (14) :5034-5040
[8]
Preparation of Tunable 3D Pillared Carbon Nanotube-Graphene Networks for High-Performance Capacitance [J].
Du, Feng ;
Yu, Dingshan ;
Dai, Liming ;
Ganguli, S. ;
Varshney, V. ;
Roy, A. K. .
CHEMISTRY OF MATERIALS, 2011, 23 (21) :4810-4816
[9]
A Three-Dimensional Carbon Nanotube/Graphene Sandwich and Its Application as Electrode in Supercapacitors [J].
Fan, Zhuangjun ;
Yan, Jun ;
Zhi, Linjie ;
Zhang, Qiang ;
Wei, Tong ;
Feng, Jing ;
Zhang, Milin ;
Qian, Weizhong ;
Wei, Fei .
ADVANCED MATERIALS, 2010, 22 (33) :3723-+
[10]
A three-dimensional nanostructure of graphite intercalated by carbon nanotubes with high cross-plane thermal conductivity and bending strength [J].
Feng, Wei ;
Qin, Mengmeng ;
Lv, Peng ;
Li, Jianpeng ;
Feng, Yiyu .
CARBON, 2014, 77 :1054-1064