Anilide ortho-arylation by using C-H activation methodology

被引：431

作者：

Daugulis, O ^{[1
]}

Zaitsev, VG ^{[1
]}

机构：

[1] Univ Houston, Dept Chem, Houston, TX 77204 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 26期

关键词：

biaryls; C-C coupling; C-H activation; homogeneous catalysis; palladium;

D O I：

10.1002/anie.200500589

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A thousand turnovers in bi- and triaryl formation: Substituted anilides have been ortho-arylated by aryl iodides under palladium catalysis (see scheme). This method is highly tolerant of the presence of additional functional groups (FGs). Even an iodo functionality on the anilide moiety and a bromo functionality on the aryl iodide are compatible with this methodology. © 2005 Wiley-VCH Verlag GmbH S. Co. KGaA.

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页码：4046 / 4048

页数：3

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