A novel protonated hexatungstoplatinate(IV), Na5.5[H2.5PtW6O24]•17H2O

被引：10

作者：

Lee, U ^{[1
]}

Joo, HC ^{[1
]}

机构：

[1] Pukyong Natl Univ, Dept Chem, Pusan 608737, South Korea

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2004年 / 60卷

关键词：

D O I：

10.1107/S1600536804002302

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The novel protonated hemiundecasodium hemipenta-hydrogen hexatungstoplatinate(IV) heptadecahydrate, Na5.5[H 2.5PtW6O24]·17H2O, crystallizes in the triclinic system in space group P1̄. The protonated O atoms were identified by considering three factors: inter-polyanion hydrogen bonds, elongation of W-O(H) bond distances, and bond angles of W-O(H)-W. The [H2.5(PtW6O24)5.5- polyanion has no inversion symmetry, and it forms a dimer, viz. [H5(PtW 6O24)2]11-, via five strong hydrogen bonds. © 2004 International Union of Crystallography Printed in Great Britain - all rights reserved.

引用

页码：I33 / I36

页数：4

共 15 条

[1] Constitution of the poly-acids [J].

Anderson, JS .

NATURE, 1937, 140 :850-850

[2]

BRADENBURG K, 1998, DIAMOND VERSION 2 1

[3] ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) [J].

Journal of Applied Crystallography, 1997, 30 (pt 5)

[4] DIPOTASSIUM HEXAHYDROGEN-ALPHA-HEXAMOLYBDOPLATINATE(IV) PENTAHYDRATE, K-2[H-6-ALPHA-PTMO6O24].5H2O [J].

LEE, U .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 :1657-1659

[5]

LEE U, 1994, B KOR CHEM SOC, V15, P37

[6] Dineodymium dihydrogen α-hexamolybdoplatinate(IV) tetradecahydrate, Nd2[H2α-PtMo6O24]•14H2O [J].

Lee, U ;

Joo, HC .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2000, 56 :E311-E312

[7] STRUCTURE OF PENTASODIUM "TRIHYDROGENHEXATUNGSTOPLATINATE(IV) ICOSAHYDRATE, NA5[H3PTW6O24].20H2O [J].

LEE, U ;

KOBAYASHI, A ;

SASAKI, Y .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1983, 39 (JUL) :817-819

[8] Pentapotassium trihydrogenhexa-tungstoplatinate(IV) hexahydrate, K5[H3PtW6O24] • 6H2O [J].

Lee, U .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2002, 58 :I130-I132

[9] THE STRUCTURE OF HEXAPOTASSIUM DISODIUM HEXATUNGSTOPLATINATE(IV) DODECAHYDRATE, K6NA2[PTW6O24].12H2O [J].

LEE, U ;

ICHIDA, H ;

KOBAYASHI, A ;

SASAKI, Y .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (JAN) :5-7

[10]

Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S0108767307043930]

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