Octakis(ferrocene)-substituted porphyrazines

被引：43

作者：

Akku, H ^{[1
]}

Gül, A ^{[1
]}

机构：

[1] Istanbul Tech Univ, Dept Chem, TR-80626 Istanbul, Turkey

来源：

TRANSITION METAL CHEMISTRY | 2001年 / 26卷 / 06期

关键词：

D O I：

10.1023/A:1012093830110

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metal-free porphyrazine and metal porphyrazinates (M = Mg, Cu, Co or Zn) substituted with eight ferrocene moieties on the periphery through flexible alkylthio-bridges have been synthesised in a multi-step reaction sequence. The new compounds have been characterised by elemental analyses, i.r., H-1- and C-13-n.m.r., u.v.-vis. and mass spectra. The electrochemical investigation of porphyrazines indicates that all the ferrocene moieties are oxidised at the same potential, confirming the lack of any interaction among ferrocene groups or between ferrocenes and the porphyrazine core.

引用

页码：689 / 694

页数：6

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