Synthesis of S-acetyl oligoarylenedithiols via Suzuki-Miyaura cross-coupling

被引：31

作者：

Operamolla, Alessandra ^{[1
]}

Hassan Omar, Omar ^{[2
]}

Babudri, Francesco ^{[1
,2
]}

Farinola, Gianluca M. ^{[1
]}

Naso, Francesco ^{[1
,2
]}

机构：

[1] Univ Bari, Dipartimento Chim, Via Orabona 4, I-70126 Bari, Italy

[2] CNR, ICCOM, Dipartimento Chim, I-70126 Bari, Italy

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 26期

关键词：

D O I：

10.1021/jo701918z

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Oligoarylenes with three or four aromatic rings, bearing two S-acetylated mercaptomethyl groups in 1,3 position on one end of the polyaromatic system and presenting various functionalities on the other terminal ring, have been synthesized by the Suzuki-Miyaura cross-coupling reaction. The use of palladium complexes with a Buchwald's phosphine as ligand allowed us to perform this coupling reaction also in the presence of benzylic S-acetyl-protected functionalities on the aromatic halide. The obtained oligoarylenes are potential novel candidates for the generation of self-assembling monolayers on metal substrates.

引用

页码：10272 / 10275

页数：4

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