An unprecedented trinucleating bridging mode (μ3-η1:η1:η1) of a tris(pyrazolyl)borate ligand in a trinuclear silver(I) complex

被引：20

作者：

Humphrey, ER ^{[1
]}

Harden, NC ^{[1
]}

Rees, LW ^{[1
]}

Jeffery, JC ^{[1
]}

McCleverty, JA ^{[1
]}

Ward, MD ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 20期

关键词：

D O I：

10.1039/a806333h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of [Ag-3(Tp(An))(2)][ClO4], where Tp(An) is tris[3-(2-methoxyphenyl)pyrazol-1-yl]hydroborate, shows a unique trinucleating bridging coordination mode for the tris(pyrazolyl)borate: each of the two ligands coordinates one pyrazolyl donor to each of the three two-coordinate Ag(I) ions, affording a triangular complex in which each face is capped by a mu(3)-eta(1):eta(1):eta(1)-tris(pyrazolyl)borate.

引用

页码：3353 / 3354

页数：2

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