Electron beam induced decomposition of chlorinated aromatic compounds in waste incinerator offgas

被引：20

作者：

Paur, HR ^{[1
]}

Baumann, W ^{[1
]}

Matzing, H ^{[1
]}

Jay, K ^{[1
]}

机构：

[1] Forschungszentrum Karlsruhe, Inst Chem Tech, D-76021 Karlsruhe, Germany

来源：

RADIATION PHYSICS AND CHEMISTRY | 1998年 / 52卷 / 1-6期

关键词：

flue gas cleaning; electron beam; waste incinerator; polychlorinated dibenzodioxins (PCDD) and -furanes (PCDF);

D O I：

10.1016/S0969-806X(98)00033-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Gaseous emissions of polychlorinated dibenzo-dioxins and -furanes (PCDD/F) in incinerator flue gas are decomposed to below 0,1 ng m(N)(-3) by the irradiation with accelerated electrons. A mobile off gas cleaning plant (AGATE-M), equipped with a 200 keV electron accelerator (EB), was used to treat a flow of 1000 m(N)(3) h(-1) of flue gas from a waste incinerator. Very high decomposition efficiencies were obtained at a dose of 5-10 kGy. A computer model (AGATE-code) was developed to analyze the gas phase chemistry of the process. The experimental and the theoretical results are reported and compared.

引用

页码：355 / 359

页数：5

共 9 条

[1]

FENGLER A, 1996, THESIS U STUTTGART

[2] SAMPLING OF POLYCHLORINATED DIBENZOFURANS (PCDF) AND DIBENZO(P)DIOXINS (PCDD) IN EMISSIONS FROM COMBUSTION FACILITIES USING AN ADSORPTION METHOD [J].

FUNCKE, W ;

LINNEMANN, H .

CHEMOSPHERE, 1992, 24 (11) :1563-1572

[3] RADIOLYTIC TREATMENT OF DIOXIN CONTAMINATED SOILS [J].

GRAY, KA ;

HILARIDES, RJ .

RADIATION PHYSICS AND CHEMISTRY, 1995, 46 (4-6) :1081-1084

[4] PILOT-SCALE TEST FOR ELECTRON-BEAM PURIFICATION OF FLUE-GAS FROM A MUNICIPAL WASTE INCINERATOR WITH SLAKED-LIME [J].

HIROTA, K ;

TOKUNAGA, O ;

MIYATA, T ;

SATO, S ;

OSADA, Y ;

SUDO, M ;

DOI, T ;

SHIBUYA, E ;

BABA, S ;

HATOMI, T ;

KOMIYA, M ;

MIYAJIMA, K .

RADIATION PHYSICS AND CHEMISTRY, 1995, 46 (4-6) :1089-1092

[5]

MACHI S, 1990, Patent No. 417714

[6]

MATZING H, 1991, ADV CHEM PHYS, V80, P315

[7]

Paur, 1991, 4 WORLD C CHEM ENG

[8] ELECTRON-BEAM PROCESSING OF INDUSTRIAL OFF-GAS BY THE MOBILE RADIATION PLANT AGATE-M [J].

PAUR, HR ;

ALBRECHT, G ;

BAUMANN, W ;

MATZING, H ;

WASCHER, T ;

MEHNERT, R ;

PRAGER, L ;

SOBOTTKA, A .

RADIATION PHYSICS AND CHEMISTRY, 1995, 46 (4-6) :1123-1127

[9]

SIRET B, 1996, INT C INC THERM TREA

← 1 →