Metal-catalyzed hydroboration and diboration of thiocarbonyls and vinyl sulfides

被引：42

作者：

Carter, CAG

Vogels, CM

Harrison, DJ

Gagnon, MKJ

Norman, DW

Langler, RF

Baker, RT

Westcott, SA

机构：

[1] Los Alamos Natl Lab, Div Chem, Los Alamos Catalysis Initiat, Los Alamos, NM 87545 USA

[2] Mt Allison Univ, Dept Chem, Sackville, NB E4L 1G8, Canada

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 11期

关键词：

D O I：

10.1021/om010135t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

alpha -Thioboronate esters are obtained directly in high yield and selectivity from metal-catalyzed additions of B-X bonds (X = H, B) to thiocarbonyl compounds and vinyl sulfides.

引用

页码：2130 / 2132

页数：3

共 40 条

[11]

Cremlyn R. J., 1996, INTRO ORGANOSULFUR C

[12]

CRUDDEN CM, COMMUNICATION

[13] Rhodium catalysed diboration of unstrained internal alkenes and a new and general route to zwitterionic [L2Rh(η6-catBcat)] (cat = 1,2-O2C6H4) complexes [J].

Dai, CY ;

Robins, EG ;

Scott, AJ ;

Clegg, W ;

Yufit, DS ;

Howard, JAK ;

Marder, TB .

CHEMICAL COMMUNICATIONS, 1998, (18) :1983-1984

[14] A new glucose-selective fluorescent bisboronic acid.: First report of strong α-furanose complexation in aqueous solution at physiological pH [J].

Eggert, H ;

Frederiksen, J ;

Morin, C ;

Norrild, JC .

JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (11) :3846-3852

[15] New perspectives for boronic esters in macrocyclic chemistry [J].

Farfán, N ;

Höpfl, H ;

Barba, V ;

Ochoa, ME ;

Santillan, R ;

Gómez, E ;

Gutiérrez, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 581 (1-2) :70-81

[16] BORANES IN SYNTHESIS .1. ASYMMETRIC-SYNTHESIS OF BETA-AMINO ALCOHOLS - A FACILE CONVERSION OF ENAMINES TO THE CORRESPONDING BETA-AMINO ALCOHOLS IN HIGH ENANTIOMERIC PURITY [J].

FISHER, GB ;

GORALSKI, CT ;

NICHOLSON, LW ;

SINGARAM, B .

TETRAHEDRON LETTERS, 1993, 34 (48) :7693-7696

[17] Direct selection for catalysis from combinatorial antibody libraries using a boronic acid probe: Primary amide bond hydrolysis [J].

Gao, CS ;

Lavey, BJ ;

Lo, CHL ;

Datta, A ;

Wentworth, P ;

Janda, KD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (10) :2211-2217

[18] 7-azabicycloheptane carboxylic acid: A proline replacement in a boroarginine thrombin inhibitor [J].

Han, W ;

Pelletier, JC ;

Mersinger, LJ ;

Kettner, CA ;

Hodge, CN .

ORGANIC LETTERS, 1999, 1 (12) :1875-1877

[19]

HOU XL, 1993, TETRAHEDRON LETT, V34, P8513

[20] Diboration of alkenes with bis(pinacolato)diboron catalysed by a platinum(0) complex [J].

Ishiyama, T ;

Yamamoto, M ;

Miyaura, N .

CHEMICAL COMMUNICATIONS, 1997, (07) :689-690

← 1 2 3 4 →