Crystal chemical and IR spectroscopic studies of intermolecular interactions in potentially prototropic organic crystals of N-substituted benz(isonicotine) hydrazides

被引：3

作者：

Chuev, II ^{[1
]}

Atovmyan, EG ^{[1
]}

Aldoshin, SM ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Chem Phys Chernoglovka, Moscow 142432, Russia

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1999年 / 474卷

关键词：

N-substituted benzhydrazides; N-substituted isonicotinehydrazides; intermolecular interactions; intermolecular hydrogen bond; crystallization;

D O I：

10.1016/S0022-2860(98)00571-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

From crystal chemical analysis of potentially prototropic N-furfurylidene (thienylidene) benzhydrazides, it was found that increasing the benzhydrazide molecular volume by S --> O replacement in the five-membered ring causes the formation of crystals with space group of lower symmetry (Pbca --> P2(1)/b). The presence of two proton acceptor centres in N-furfurylidene (thienylidene) isonicotinehydrazide (IH) molecules (N-Py and C=O) leads to the occurrence of one of two types of intermolecular hydrogen bond (IB) ( > C=O...HN < and > N-Py...HN <) depending on the crystallization conditions. The process of IH crystallization was studied by a crystal chemical approach. Analysis of the N-H valence vibration intensity for IH showed that specific CH...O and S...O intermolecular interactions play an important role in cooperative interactions of > N-Py...HN < IB. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：177 / 186

页数：10

共 5 条

[1]

ALDOSHIN SM, 1994, CORRELATIONS TRANSFO, P79

[2]

ATOVMYAN EG, IN PRESS RUSS CHEM B

[3] Infrared spectra and structure of hydrogen bonds in N′-substituted isonicotinic hydrazides formed by crystallization from solution and via solid phase transformations [J].

Atovmyan, YG ;

Nikonova, LA ;

Chuev, II ;

Utenyshev, AN ;

Aldoshina, MZ ;

Aldoshin, SM .

JOURNAL OF MOLECULAR STRUCTURE, 1999, 474 :167-175

[4] X-ray and IR spectroscopic studies of specific intermolecular interactions in N'-substituted isonicotinohydrazides [J].

Chuev, II ;

Aldoshin, SM ;

Atovmyan, EG ;

Frolov, DB ;

Utenyshev, AN .

RUSSIAN CHEMICAL BULLETIN, 1996, 45 (04) :851-855

[5]

KROON J, 1996, INT UNION CRYSTALLOG, V4, P19

← 1 →