Measuring aromaticity by NMR

被引：295

作者：

Mitchell, RH ^{[1
]}

机构：

[1] Univ Victoria, Dept Chem, Victoria, BC V8W 3V6, Canada

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 05期

关键词：

D O I：

10.1021/cr990359+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A study of measurement of aromaticity was carried out by using NMR. The annulenes was also synthesized such that analysis of NMR data can yield information on their relative aromaticities. The results showed that the annulene 34 is strongly diatropic and annulene 98 is also diatropoic.

引用

页码：1301 / 1315

页数：15

共 106 条

[61] BENZANNELATED ANNULENES .6. TOWARD THE UNDERSTANDING OF BENZANNELATED ANNULENES - SYNTHESIS AND PROPERTIES OF [A]-RING MONOBENZANNELATED DIHYDROPYRENES [J].

MITCHELL, RH ;

CARRUTHERS, RJ ;

MAZUCH, L ;

DINGLE, TW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (09) :2544-2551

[62] BENZANNELATED ANNULENES .7. TOWARD THE UNDERSTANDING OF BENZANNELATED ANNULENES - SYNTHESIS AND PROPERTIES OF AN [E]-RING MONOBENZANNELATED DIHYDROPYRENE [J].

MITCHELL, RH ;

YAN, JSH ;

DINGLE, TW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (09) :2551-2559

[63]

MITCHELL RH, 1992, TETRAHEDRON LETT, V32, P6319

[64]

MITCHELL RH, 1975, TETRAHEDRON LETT, V16, P4331

[65]

MITCHELL RH, 1989, ADV THEORET INTEREST, V1, P135

[66]

MITCHELL RH, 2000, IN PRESS TETRAHEDRON

[67]

MULLEN K, 1987, J AM CHEM SOC, V109, P4992, DOI 10.1021/ja00250a038

[68]

MULLEN K, 1982, J AM CHEM SOC, V104, P5403

[69] AN INDUCED BARRIER TO ROTATION ABOUT THE ETA-6-ARENE METAL BOND IN CENTRALLY BOUND BENT-TERPHENYLENECHROMIUM TRICARBONYL - A GAUGE FOR AROMATIC CHARACTER AND BOND LOCALIZATION [J].

NAMBU, M ;

SIEGEL, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (11) :3675-3676

[70] REACTIONS OF 4-BROMO-1,6-METHANO[10]ANNULENE-3-CARBALDEHYDE - SYNTHESES OF 3,4-HETEROANELLATED 1,6-METHANO[10]ANNULENES [J].

NEIDLEIN, R ;

SCHRODER, G .

HELVETICA CHIMICA ACTA, 1992, 75 (03) :825-832

← 2 3 4 5 6 7 8 9 10 11 →