[Re2(μ-1,2,4-triazolate)2(μ-OH)(CO)6]-:: a novel metalloligand for the construction of flexible porous coordination networks

被引：8

作者：

Barea, Elisa ^{[1
,2
]}

Rodriguez-Dieguez, Antonio ^{[3
]}

Navarro, Jorge A. R. ^{[4
]}

D'Alfonso, Giuseppe ^{[1
,2
]}

Sironi, Angelo ^{[3
]}

机构：

[1] Univ Milan, Dipartimento Chim Inorgan Metallorgan & Analit, I-20133 Milan, Italy

[2] CNR, ISTM, I-20133 Milan, Italy

[3] Univ Milan, Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy

[4] Univ Granada, Dept Quim Inorgan, E-18071 Granada, Spain

来源：

DALTON TRANSACTIONS | 2008年 / 14期

关键词：

D O I：

10.1039/b800591e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The [Re-2(mu-trz-kappa N-1:kappa N-2)(2)(mu-OH)(CO)(6)](-) (trz = 1,2,4-triazolate) organometallic anion reacts with Ag+ to afford a 2D organometallic/coordination network, [Ag{Re-2(mu(3)-trz- kappa N-1: kappa N-2: kappa N-4)(2)(mu(3)-OH)(CO)(6)}](n) center dot 4nCH(3)OH, which shows dynamic structural changes triggered by solid - liquid guest exchange processes.

引用

页码：1825 / 1827

页数：3