Myth or Reality? Fixation of Carbon Dioxide into Complex Organic Matter under Mild Conditions

被引:245
作者
Martin, Ruben [1 ]
Kleij, Arjan W. [1 ,2 ]
机构
[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain
[2] Catalan Inst Res & Adv Studies ICREA, Barcelona 08010, Spain
关键词
carbon dioxide; fixation; homogeneous catalysis; organic chemistry; sustainability; CATALYZED DIRECT CARBOXYLATION; ALTERNATING COPOLYMERIZATION; ORGANOMETALLIC CHEMISTRY; CYCLOHEXENE OXIDE; H BONDS; EPOXIDES; CO2;
D O I
10.1002/cssc.201100102
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
And mild it is: This Highlight covers the most recent developments in CO2 fixation by homogeneous catalytic methods under mild reactions conditions. A particular focus is given to two main product categories: the formation of carboxylic acids (and derivatives) from sources comprising reactive C-H bonds, and the integration of CO2 into (functionalized) epoxides giving rise to either cyclic carbonate or poly(carbonate) structures. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1259 / 1263
页数:5
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