2,2-Dimethyl cyclopentanones by acid catalyzed ring expansion of isopropenylcyclobutanols.: A short synthesis of (±)-α-cuparenone and (±)-herbertene

被引：30

作者：

Bernard, AM ^{[1
]}

Frongia, A ^{[1
]}

Secci, F ^{[1
]}

Piras, PP ^{[1
]}

机构：

[1] Univ Cagliari, Dipartimento Sci Chim, I-09042 Cagliari, Italy

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 30期

关键词：

D O I：

10.1039/b505707h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2,2-Dimethyl cyclopentanones are readily prepared by acid catalyzed ring expansion of isopropenylcyclobutanols; the method allows ready access to the family of sesquiterpenes cuparanes and herbertanes, as demonstrated by the synthesis of (+/-)-alpha-cuparenone and the direct precursor of (+/-)-herbertene.

引用

页码：3853 / 3855

页数：3

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