Pauson-Khand approach to chiral, diastereomerically pure group 4 ansa-metallocene complexes.

被引：14

作者：

Grossman, RB ^{[1
]}

机构：

[1] Univ Kentucky, Dept Chem, Lexington, KY 40506 USA

来源：

TETRAHEDRON | 1999年 / 55卷 / 04期

关键词：

transition metals; metalation; Pauson-Khand reaction; elimination reactions; polycyclic aliphatic compounds;

D O I：

10.1016/S0040-4020(98)01099-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The C-2-symmetric bis(1,6-enynes) threo-1,10-diphenyl-5,6-divinyl-1,9-decadiyn and threo-9,1 0-divinyl-5,13-octadecadiyne undergo the intramolecular Pauson-Khand reaction regio- and stereoselectively to give C(2)symmetric bis(enones) with two bicyclo[3.3.0]octyl moieties joined at the C6 position. Experiments aimed at converting the bis(enones) into chiral, diastereopure ansa-bridged group 4 metallocene complexes are described. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

收藏

页码：919 / 934

页数：16

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