A selective synthesis of the 1,3,4-triphospholide anion

被引：30

作者：

Fish, C

Green, M

Jeffery, JC

Kilby, RJ

Lynam, JM

Russell, CA

Willans, CE

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[2] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 24期

关键词：

D O I：

10.1021/om050766d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mg-2(mu-Cl)(3)(THF)(6)][2,5-((CBu)-Bu-t)(2)-1,3,4-P-3] and K[2,5-((CBU)-B-t)(2)-1,3,4-P-3] are formed quantitatively from reduction of the tricyclic-triphosphorus compound ClP3-((CBU)-B-t)(2) with Mg or K; the mechanistic insights gained from these studies lead to a new and "economic" synthesis of the [2,5-((CBU)-B-t)(2)-1,3,4-P-3](-) anion from the phosphalkyne (BuC)-Bu-t equivalent to P.

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收藏

页码：5789 / 5791

页数：3

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