Self-organized buffer layers in organic solar cells

被引：242

作者：

Wei, Qingshuo ^{[1
]}

Nishizawa, Takeshi ^{[1
]}

Tajima, Keisuke ^{[1
]}

Hashimoto, Kazuhito ^{[1
,2
]}

机构：

[1] Univ Tokyo, Bunkyo Ku, Dept Appl Chem, Sch Engn, Tokyo 1138656, Japan

[2] JST, ERATO, HASHIMOTO Light Energy Convers Project, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ADVANCED MATERIALS | 2008年 / 20卷 / 11期

关键词：

D O I：

10.1002/adma.200792876

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A fullerene derivative with a fluorocarbon chain is applied in bulk-heterojunction polymer solar cells (see figure). When a small amount of F-PCBM is mixed in, it spontaneously migrates to the surface of the organic layer during spin-casting owing to the low surface energy of the fluorocarbon. A very thin buffer layer between the polymer and the metal electrode is formed in one step, resulting in improved photovoltaic performance.

引用

页码：2211 / +

页数：7

共 32 条

[21] Self-assembled multilayers of nanocomponents [J].

Krishnan, R. S. ;

Mackay, Michael E. ;

Duxbury, Phillip M. ;

Pastor, Alicia ;

Hawker, Craig J. ;

Van Horn, Brooke ;

Asokan, Subashini ;

Wong, Michael S. .

NANO LETTERS, 2007, 7 (02) :484-489

[22] PERSPECTIVES IN SUPRAMOLECULAR CHEMISTRY - FROM MOLECULAR RECOGNITION TOWARDS MOLECULAR INFORMATION-PROCESSING AND SELF-ORGANIZATION [J].

LEHN, JM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (11) :1304-1319

[23] Efficient inverted polymer solar cells [J].

Li, G. ;

Chu, C. -W. ;

Shrotriya, V. ;

Huang, J. ;

Yang, Y. .

APPLIED PHYSICS LETTERS, 2006, 88 (25)

[24] Supramolecular formation of fibrous nanostructure in donor-acceptor dyad Mint [J].

Nishizawa, Takeshi ;

Tajima, Keisuke ;

Hashimoto, Kazuhito .

JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (23) :2440-2445

[25] Electronic energy states of organic interfaces studied by low-energy ultraviolet photoemission spectroscopy [J].

Onoda, M ;

Tada, K ;

Nakayama, H .

JOURNAL OF APPLIED PHYSICS, 1999, 86 (04) :2110-2115

[26] LATERALLY INHOMOGENEOUS SURFACE-POTENTIAL DISTRIBUTION AND PHOTOVOLTAGE AT CLUSTERED IN/WSE2(0001) INTERFACES [J].

SCHLAF, R ;

KLEIN, A ;

PETTENKOFER, C ;

JAEGERMANN, W .

PHYSICAL REVIEW B, 1993, 48 (19) :14242-14252

[27] Transition metal oxides as the buffer layer for polymer photovoltaic cells - art. no. 073508 [J].

Shrotriya, V ;

Li, G ;

Yao, Y ;

Chu, CW ;

Yang, Y .

APPLIED PHYSICS LETTERS, 2006, 88 (07)

[28] Regiorandom poly(3-hexylthiophene) on gold: Interfacial electronic structures and photoexcitation kinetics [J].

Sohn, Youngku ;

Stuckless, John T. .

CHEMICAL PHYSICS LETTERS, 2007, 436 (1-3) :228-232

[29] MOLECULAR SELF-ASSEMBLY AND NANOCHEMISTRY - A CHEMICAL STRATEGY FOR THE SYNTHESIS OF NANOSTRUCTURES [J].

WHITESIDES, GM ;

MATHIAS, JP ;

SETO, CT .

SCIENCE, 1991, 254 (5036) :1312-1319

[30] Polymer solar cells and infrared light emitting diodes:: Dual function low bandgap polymer [J].

Winder, C ;

Mühlbacher, D ;

Neugebauer, H ;

Sariciftci, NS ;

Brabec, C ;

Janssen, RAJ ;

Hummelen, JK .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2002, 385 :213-220

← 1 2 3 4 →