All-water-solution processed solar cells based on PPV and TiO2 nanocrystals

被引：15

作者：

Dong, Qingfeng ^{[1
]}

Yu, Weili ^{[1
]}

Li, Zaifang ^{[1
]}

Yao, Shiyu ^{[1
]}

Zhang, Xiaoyu ^{[1
]}

Yang, Bai ^{[1
]}

Im, Chan ^{[2
]}

Tian, Wenjing ^{[1
]}

机构：

[1] Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China

[2] Konkuk Univ, Dept Chem, Seoul 143701, South Korea

来源：

SOLAR ENERGY MATERIALS AND SOLAR CELLS | 2012年 / 104卷

基金：

中国国家自然科学基金;

关键词：

Hybrid solar cells; Environmentally friendly; Photovoltaic; Morphology; PHOTOVOLTAIC CELLS; POLYMER; POLYTHIOPHENE; PERFORMANCE; FABRICATION; STABILITY;

D O I：

10.1016/j.solmat.2012.04.024

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

In this work, we present an all-water-solution processed polymer/nanocrystals (NCs) hybrid solar cell (HSC) with bulk heterojunction (BHJ) architecture with donor material poly(phenylene vinylene) (PPV) and acceptor material anatase TiO2 NCs. After spin-coating a water solution containing PPV precursor and TiO2 NCs, the active layer is achieved after a simple annealing process. The influences of PPV:TiO2 and their morphology on the photovoltaic performance of HSCs were investigated. By changing the ratio of PPV to TiO2, the morphology of the active layer can be controlled and the photovoltaic performance of polymer/NCs hybrid solar can be improved. The hybrid solar cells with a PPV:TiO2 blend ratio 1:3 present the best performance with the PCE of 0.11%. This work provides an alternative way to fabricate environmentally friendly, low cost, and high throughout polymer solar cells by using water as the processing solvent. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：75 / 80

页数：6

共 39 条

[1] Aqueous Processing of Low-Band-Gap Polymer Solar Cells Using Roll-to-Roll Methods [J].

Andersen, Thomas R. ;

Larsen-Olsen, Thue T. ;

Andreasen, Birgitta ;

Bottiger, Arvid P. L. ;

Carle, Jon E. ;

Helgesen, Martin ;

Bundgaard, Eva ;

Norrman, Kion ;

Andreasen, Jens W. ;

Jorgensen, Mikkel ;

Krebs, Frederik C. .

ACS NANO, 2011, 5 (05) :4188-4196

[2] An explanation for the high stability of polycarboxythiophenes in photovoltaic devices- A solid-state NMR dipolar recoupling study [J].

Bierring, Morten ;

Nielsen, Julie S. ;

Siu, Ana ;

Nielsen, Niels Chr. ;

Krebs, Frederik C. .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2008, 92 (07) :772-784

[3] LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS [J].

BURROUGHES, JH ;

BRADLEY, DDC ;

BROWN, AR ;

MARKS, RN ;

MACKAY, K ;

FRIEND, RH ;

BURN, PL ;

HOLMES, AB .

NATURE, 1990, 347 (6293) :539-541

[4] Study on photoelectrochemical solar cells of nanocrystalline Cd0.7Zn0.3Se -water soluble conjugated polymer [J].

Chavhan, S. D. ;

Mane, R. S. ;

Lee, Wonjoo ;

Senthilarasu, S. ;

Han, Sung-Hwan ;

Lee, J. ;

Lee, Soo-Hyoung .

ELECTROCHIMICA ACTA, 2009, 54 (11) :3169-3175

[5] Polymer solar cells with enhanced open-circuit voltage and efficiency [J].

Chen, Hsiang-Yu ;

Hou, Jianhui ;

Zhang, Shaoqing ;

Liang, Yongye ;

Yang, Guanwen ;

Yang, Yang ;

Yu, Luping ;

Wu, Yue ;

Li, Gang .

NATURE PHOTONICS, 2009, 3 (11) :649-653

[6] SYNTHESIS, DOPING, AND ELECTRICAL-CONDUCTIVITY OF HIGH-MOLECULAR-WEIGHT POLY(PARA-PHENYLENE VINYLENE) [J].

GAGNON, DR ;

CAPISTRAN, JD ;

KARASZ, FE ;

LENZ, RW ;

ANTOUN, S .

POLYMER, 1987, 28 (04) :567-573

[7] Fill factor in organic solar cells [J].

Gupta, Dhritiman ;

Mukhopadhyay, Sabyasachi ;

Narayan, K. S. .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2010, 94 (08) :1309-1313

[8] Water based preparation method for 'green' solid-state polythiophene solar cells [J].

Haeldermans, I. ;

Truijen, I. ;

Vandewal, K. ;

Moons, W. ;

Van Bael, M. K. ;

D'Haen, J. ;

Manca, J. V. ;

Mullens, J. .

THIN SOLID FILMS, 2008, 516 (20) :7245-7250

[9] Stability of Polymer Solar Cells [J].

Jorgensen, Mikkel ;

Norrman, Kion ;

Gevorgyan, Suren A. ;

Tromholt, Thomas ;

Andreasen, Birgitta ;

Krebs, Frederik C. .

ADVANCED MATERIALS, 2012, 24 (05) :580-612

[10] Efficient tandem polymer solar cells fabricated by all-solution processing [J].

Kim, Jin Young ;

Lee, Kwanghee ;

Coates, Nelson E. ;

Moses, Daniel ;

Nguyen, Thuc-Quyen ;

Dante, Mark ;

Heeger, Alan J. .

SCIENCE, 2007, 317 (5835) :222-225

← 1 2 3 4 →