Bent and stretched but not yet to the breaking point:: C8-C16 sp carbon chains that span two platinum atoms and the first structurally characterized 1,3,5,7,9,11,13,15-octayne

被引:89
作者
Mohr, W [1 ]
Stahl, J [1 ]
Hampel, F [1 ]
Gladysz, JA [1 ]
机构
[1] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany
关键词
D O I
10.1021/ic010309z
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
What kind of Maxwell's Demon is bending this C-12 chain in the crystal lattice? When "stretched" by an additional four carbons, it straightens considerably, to a gentle S-shape. <Graphics>
引用
收藏
页码:3263 / 3264
页数:2
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