Surface treatment of carbon electrodes by electron beam irradiation

被引：9

作者：

Endo, E

Kihira, T

Yamada, S

Imoto, H

Sekai, K

机构：

[1] Sony Corp, Frontier Sci Labs, Yokohama, Kanagawa 2400036, Japan

[2] Sony Corp, R&D Patent Dept, Yokohama, Kanagawa 2400036, Japan

[3] Sony Corp, CNC Co, Yokohama, Kanagawa 2400036, Japan

来源：

JOURNAL OF POWER SOURCES | 2001年 / 93卷 / 1-2期

关键词：

electron beam irradiation; carbon electrode; surface treatment; lithium-ion battery;

D O I：

10.1016/S0378-7753(00)00581-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An electron beam (EB) was irradiated on carbon anodes of lithium-ion secondary batteries. The discharge capacity was increased by 19 mAh g(-1) in the mesocarbon microbeads electrode and by 55 mAh g(-1) in the coffee-bean derived carbon electrode. X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy were used to observe the surface changes which included a reduction in the amount of binder and structural changes in the carbon materials. (C) 2001 Elsevier Science B.V. Al rights reserved.

引用

页码：215 / 223

页数：9

共 31 条

[1] State-of-the-art overview: ion beam surface modification of polymers towards improving tribological properties [J].

Dong, H ;

Bell, T .

SURFACE & COATINGS TECHNOLOGY, 1999, 111 (01) :29-40

[2] Chemical oxidation: A route to enhanced capacity in Li-ion graphite anodes [J].

EinEli, Y ;

Koch, VR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (09) :2968-2973

[3] Surface roughening by electron beam heating [J].

Grozea, D ;

Landree, E ;

Marks, LD .

APPLIED PHYSICS LETTERS, 1997, 71 (16) :2301-2303

[4]

IMOTO H, 1993, ELECTROCHEMICAL SOC, P9

[5]

IMOTO H, 1994, ELECTROCHEMICAL SOC, P43

[6] Influence of Graphite Surface Modifications on Lithium Intercalation Properties [J].

Joho, Felix ;

Novak, Petr ;

Haas, Otto ;

Monnier, Alain ;

Fischer, Francis .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1998, 310 :383-388

[7] Observations of GaAs/CaF2 heterointerface formation by electron beam surface modification and its effects [J].

Kawasaki, K ;

Tsutsui, K .

APPLIED SURFACE SCIENCE, 1997, 117 :753-757

[8] SURFACE MODIFICATION OF PITCH-BASED CARBON-FIBER FOR THE IMPROVEMENT OF ELECTROCHEMICAL LITHIUM INTERCALATION [J].

KIKUCHI, M ;

IKEZAWA, Y ;

TAKAMURA, T .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 396 (1-2) :451-455

[9] CHARACTERIZATION OF DIAMOND FILMS BY RAMAN-SPECTROSCOPY [J].

KNIGHT, DS ;

WHITE, WB .

JOURNAL OF MATERIALS RESEARCH, 1989, 4 (02) :385-393

[10] The influence of polytetrafluorethylene reduction on the capacity loss of the carbon anode for lithium ion batteries [J].

Li, GB ;

Xue, RJ ;

Chen, LQ .

SOLID STATE IONICS, 1996, 90 (1-4) :221-225

← 1 2 3 4 →