Behavioral patterns of heterometallic cuboidal derivatives of [M3Q4(H2O)9]4+ (M = Mo, W; Q = S, Se)

被引：162

作者：

Hernandez-Molina, R

Sokolov, MN

Sykes, AG ^{[1
]}

机构：

[1] Univ La Laguna, Dept Quim Inorgan, La Laguna 38200, Spain

[2] Russian Acad Sci, Inst Inorgan Chem, Novosibirsk 630090, Russia

[3] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2001年 / 34卷 / 03期

关键词：

D O I：

10.1021/ar960152s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This Account reports recent progress in the study of some similar to 20 heterometal derivatives of [Mo3S4(H2O)(9)](4+) with reference also to W and Se analogues. Single cubes (3:1) and corner-shared double cubes (6:1), as well as dimers of the 3:1 single cubes, are considered. A classification of the heterometals as subtypes A, B, and C is introduced.

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页码：223 / 230

页数：8

相关论文

共 38 条

[1] Molybdenum-copper-sulfur Mo3CuS4 cubes [J].

Akashi, H ;

Shibahara, T .

INORGANICA CHIMICA ACTA, 2000, 300 :572-580

[2]

AKASHI H, 1999, 18 IUCR C GLASG AUG

[3] Bonding in Mo3Mp′S4 cubane-type clusters:: Variations in electronic structure when M′ is a main group or transition metal [J].

Bahn, CS ;

Tan, A ;

Harris, S .

INORGANIC CHEMISTRY, 1998, 37 (11) :2770-2778

[4] SYNTHETIC, STRUCTURAL, AND THEORETICAL-STUDIES ON THE ELECTRON-DEFICIENT CUBANES (RC5H4)4TI4S4, (RC5H4)4V4S4, AND [(RC5H4)4V4S4]+ [J].

DARKWA, J ;

LOCKEMEYER, JR ;

BOYD, PDW ;

RAUCHFUSS, TB ;

RHEINGOLD, AL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (01) :141-149

[5] ELECTRON-TRANSFER REACTIVITY OF CUBOIDAL HETEROMETALLIC MO(3)MS(4) CLUSTERS IN AQUEOUS ACIDIC SOLUTIONS [J].

DIMMOCK, PW ;

SAYSELL, DM ;

SYKES, AG .

INORGANICA CHIMICA ACTA, 1994, 225 (1-2) :157-162

[6] Preparation, structure and properties of trinuclear [M3Se4(CN)(9)](5-) (M=Mo or W) complexes obtained from M3Se7 core compounds and related studies [J].

Fedin, VP ;

Lamprecht, GJ ;

Kohzuma, T ;

Clegg, W ;

Elsegood, MRJ ;

Sykes, AG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (10) :1747-1751

[7] Synthesis, structure, and properties of molybdenum and tungsten cyano complexes with cuboidal M4(μ3-E)4 (M = Mo, W; E = S, Se, Te) cores [J].

Fedin, VP ;

Kalinina, IV ;

Samsonenko, DG ;

Mironov, YV ;

Sokolov, MN ;

Tkachev, SV ;

Virovets, AV ;

Podberezskaya, NV ;

Elsegood, MRJ ;

Clegg, W ;

Sykes, AG .

INORGANIC CHEMISTRY, 1999, 38 (09) :1956-1965

[8] Preparation of heterometallic single cubes [W(3)MS(4)(H2O)(12)](n+) (M=In, Ge or Sn) and the first corner-share double cubes [W6SnS8(H2O)(18)](8+) and [W3Mo3SnS8(H2O)(18)](8+) as derivatives of [W3S4(H2O)(9)](4+) [J].

Fedin, VP ;

Sokolov, MN ;

Sykes, AG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (21) :4089-4092

[9] Synthesis and structure of a tetranuclear niobium telluride cuboidal cluster with a central μ4-O ligand [J].

Fedin, VP ;

Kalinina, IV ;

Virovets, AV ;

Podberezskaya, NV ;

Neretin, IS ;

Slovokhotov, YL .

CHEMICAL COMMUNICATIONS, 1998, (23) :2579-2580

[10]

FONTECILLACAMPS JC, 1999, ADV INORG CHEM, V47, P304

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