Stabilization of the Heavy Methylene Analogues, GeH2 and SnH2, within the Coordination Sphere of a Transition Metal

被引：155

作者：

Al-Rafia, S. M. Ibrahim ^{[1
]}

Malcolm, Adam C. ^{[1
]}

Liew, Sean K. ^{[1
]}

Ferguson, Michael J. ^{[1
]}

Rivard, Eric ^{[1
]}

机构：

[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 04期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

MAIN-GROUP; HETEROCYCLIC CARBENES; TIN; C6H2-2,4,6-I-PR-3; GERMANIUM(II); REACTIVITY; COMPLEXES; PRODUCTS; SILICON; ADDUCT;

D O I：

10.1021/ja1106223

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The heavy group 14 methylene analogues, EH2, (E = Ge and Sn) have been stabilized via efficient methods, thus enabling the chemistry of these novel inorganic hydrides to be explored in depth.

引用

页码：777 / 779

页数：3

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